Enhancement in lithium storage performances of SiO2/graphene-based nanocomposites prepared by low cost and facile approach

Journal of Materials Science: Materials in Electronics - The new nanocomposites of silicon dioxide/reduced graphene oxide (SiO2/rGO) and silicon dioxide/nitrogen-doped reduced graphene oxide...     

Optical-luminescence properties of ZnO and TiO2 nanopowders obtained by pulsed laser reactive ablation

Journal of Materials Science: Materials in Electronics - The ZnO and TiO2 nanopowders have been prepared by means of the pulsed laser reactive ablation of metallic (Zn, Ti) targets. The Structural,...     

Dielectric performance and conductive mechanism of KNN-based ceramics prepared via sol–gel core–shell process

Journal of Materials Science: Materials in Electronics - 0.95(Li0.02Na0.50K0.48)(Nb0.95Sb0.05)O3–0.05AgTaO3@BaZrO3 (LNKNbSAT@BZ) lead-free ceramics were prepared via a sol–gel...     

Co-precipitation synthesis of ZnAl2O4: Cr3+ phosphor for better light penetration in pc-LED

Cr doped ZnAl₂O₄ spinel samples were prepared by the traditional solid state reaction and co-precipitation synthetic route, and the results suggest that the co-precipitation method has some superiority in contrast to the solid state reaction method. XRD, FT-IR, and XPS spectra confirmed that the well-crystallized spinel cubic phase of ZnAl₂O₄: Cr³⁺ samples were successfully formed. The morphology of the samples was investigated by FE-SEM and FE-TEM, and the results show that the samples by the co-precipitation route can generate a smaller size of particles compared to the solid state reaction. Photoluminescence excitation spectra monitored at 686 nm are comprised of two broad excitation bands near 530 nm and 395 nm, and the emission spectra show emissions ranging from 640 to 780 nm, due to the ²E?→?⁴A₂ spin-forbidden transition of Cr³⁺ ions in spinel lattices. The optimized concentration monitored at 686 nm is 1%, while at 693 nm is 3.5%. Compared with the samples by solid state reaction method, the samples by co-precipitation method show preferable luminescent properties, such as the higher photoluminescence intensity and higher quantum efficiency. Several phosphor-converted LEDs were to investigate the applicability of the prepared samples. The results confirm that the phosphor has potential applications in plant growth and supplementing the red region in white-LEDs and the phosphors prepared by co-precipitation are more suitable to be used in phosphor-converted LED devices due to their preferable luminescent properties.

     

Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

Annealing of Mineral-Like Host Matrices for High-Level Waste Immobilization

Inorganic Materials - We have studied the effect of annealing on the chemical and physical properties of mineral-like host matrices for immobilization of the rare-earth–actinide fraction from...     

Eco-friendly approach for preparation of hybrid silica aerogel via freeze drying method

Journal of Materials Science - In this paper, an eco-friendly method of producing hybrid silica aerogels by freeze-drying method (FD) is proposed. In the freeze-drying system, deionized water was...     

A medical Chatbot using machine learning and natural language understanding

Multimedia Tools and Applications - For people with busy schedules, travelling to and from a hospital for treatment is considerably time consuming, which leads them to ignore their health problems....